Name | Lithium chloride hydrate |
Synonyms | (99.9 LI) PURATREM Lithium chloride hydrate Lithium chloride,crystal LITHIUM CHLORIDE HYDRATE LITHIUM CHLORIDE 1-HYDRATE Lithium chloride momohydrate LITHIUM CHLORIDE MONOHYDRATE LITHIUM CHLORIDE MONOHYDRATE 250 G Lithium chloride monohydrate (metals basis) |
CAS | 16712-20-2 |
EINECS | 678-843-4 |
InChI | InChI=1/ClH.Li.H2O/h1H;;1H2/q;+1;/p-1 |
Molecular Formula | ClH2LiO |
Molar Mass | 60.41 |
Density | 1.78 |
Melting Point | >98°C -H₂O |
Boling Point | 1382℃ |
Water Solubility | Soluble in water. |
Vapor Presure | 24.5mmHg at 25°C |
Appearance | White crystal |
Color | White |
Merck | 14,5528 |
Storage Condition | Room Temprature |
Sensitive | Hygroscopic |
MDL | MFCD00011078 |
Hazard Symbols | Xn - Harmful |
Risk Codes | R22 - Harmful if swallowed R36/37/38 - Irritating to eyes, respiratory system and skin. |
Safety Description | 26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. |
WGK Germany | 1 |
FLUKA BRAND F CODES | 3 |
TSCA | Yes |
Reference Show more | 1. Zhao Yu, Liu Yang. Study on the Protective Mechanism of Compound Danshen Dropping Pills on Epileptic Model Rats through JAK-STAT Pathway [J]. Evaluation and Analysis of Drug Use in Chinese Hospitals, Volume 20, Issue 7, 2020, 828-831,835 pages, ISTIC, 2020. 2. Feng Lei, Xie Liping, Zhang Haiping, the effect and mechanism of silencing Rbfox1 on the biological behavior of hippocampal neurons in epileptic model rats [J]. Journal of Difficult Diseases, Volume 19, No. 8, 202020, pp. 835-838, ISTIC CA, 2020. 3. Yang Ziyin, Li Ning, Huang Jun, Li Jiayu, Gao Anliang. Effects of Src kinase inhibitor PP2 on brain edema formation and ERK1/2 and P38 signaling pathways in epileptic rats [J]. Journal of Shanxi Medical University, 2021,52(02):173-178. |
white crystals. Deliquescence. Soluble in water can dissolve in water, alcohol, acetone, amyl alcohol, pyridine and nitrobenzene, higher than 98 deg C to lose water of crystallization, aqueous solution is neutral or slightly alkaline.
pure lithium carbonate was gradually added to hydrochloric acid to make lithium carbonate excessive. After the completion of the reaction, filtration, evaporation of the filtrate to precipitate most of the crystals, cooling, Suction filtration, pure lithium chloride can be obtained.
A raw material for preparing lithium metal. Used as aluminum welding agent, air conditioning desiccant, manufacturing pyrotechnic and special cement raw materials, in the battery industry for the production of lithium manganese battery electrolyte.
(anhydrous) intraperitoneal injection of LDso in mice: 990mg/kg; Intraperitoneal injection of LDso in rats: 600mg/kg; Intravenous injection of LDso in rats: 4.8 mg/kg.
introduction | lithium chloride is white and a regular crystal with NaC1 type face-centered lattice (a = 0.513nm). Melting point 605 ℃, boiling point 136 ℃. Very hygroscopic, soluble in methanol, ethanol, pyridine, ether, acetone, slightly soluble in liquid ammonia. Lithium chloride monohydrate is a compound composed of lithium chloride and water. |
Use | Due to the controlled nuclear fusion reaction of lithium chloride and its derivatives, aluminum-lithium alloys, lithium-ion batteries, nonlinear optical materials in optical communications, etc. The demand for raw material lithium chloride has increased significantly, and this trend is becoming more and more obvious, which makes the production of lithium chloride show unprecedented good prospects. Lithium chloride monohydrate is a compound composed of lithium chloride and water. |
production method | 1. gradually add pure lithium carbonate to hydrochloric acid to make lithium carbonate excessive. After the reaction is completed, filter, evaporate the filtrate until most of the crystals are precipitated, and then cool and filter to obtain pure lithium chloride. 2. Preparation method Add water to industrial lithium carbonate, heat and stir, filter while hot, spin dry, and repeat twice to remove most of the K Na plasma. The soaked raw material lithium carbonate is slowly added to hydrochloric acid with a relative density of 1.19, and the reaction is carried out: after the reaction, a small amount of undissolved lithium carbonate should be left, and the pH of the solution at this time is 6~7. Filter out the insoluble matter, add hydrochloric acid to the filtrate to pH = 3-then add an appropriate amount of barium chloride, let it stand, after the barium sulfate is completely precipitated, add lithium hydroxide to the solution = 1 2, add an appropriate amount of oxalic acid, precipitate Ca 2 Mg 2 ions, filter, evaporate the filtrate until a large amount of crystallization is precipitated, cool with ice water, continue crystallization, and drain the reagent lithium chloride monohydrate is obtained. |